It complicated and can be done (Well at least I could do it on an MT300N-V2, so I am guessing it can be done on AR300).

I would avoid the router config altogether.

Why not on windows:
Set a static IP address on the Wifi interface uner IP4 settings as you do at the moment?
Then go to advanced and add the ip address and mask for the 2nd network?

It would avoid swapping IP addresses on PC wifi all the time. Is 30 seconds to setup.

Simon