Hello haynlyn,
Are these Work domains “internal”. I.E you need to reach them over over your work VPN, or could I browse to them from my home?
Is the work VPN setup on your router, or on your laptop?
I am thinking some sort of DNS problem, i.e. you need to use the DNS server supplied by the Work VPN to resolve their names?
Alternatively…
If these are internal IP addresses, I wonder if your work VPN is assuming it is going to be the default gateway (on the laptop), and does not push out the static routes, so when your default gateway is say the Wireshark VPN you can only get to the top level of the Work VPN.
Hope the above makes sense, just need a bit more info to help debug.
Simon