Is This Configuration Possible?

I’d consider removing your primary router fr the equation. The Beryl can handle Multi-WAN via GL GUI → Network → Multi-WAN.

… but you answer your question: yeah, I’m sure you could do it. Anything you don’t see within the GL GUI can be handled via LuCI (GL GUI → Advanced Settings) or via SSH to edit conf if you’re like me & don’t care for OpenWrt’s UCI.

Hypothetically it could just be a matter of setting the Beryl to set the Guest SSID’s client MACs to force’em to only use a specific interface (eg: tethering). iptables is used & Beryl interfaces are defined @ /etc/config/network. This might give something for a starting point:

Don’t forget to backup your setup: