OK. The MT300N-V2 arrived today. Soldered in a header and had a poke around. By default with the 2.27 firmware, GPIO4 GPIO5 GPIO45 and GPIO46 on the inner row of the header are all available. As described in https://openwrt.org/docs/techref/hardware/port.gpio I was able to enable and toggle them using
# echo "4" > /sys/class/gpio/export
# echo "out" > /sys/class/gpio/gpio4/direction
# echo "0" > /sys/class/gpio/gpio4/value
# echo "1" > /sys/class/gpio/gpio4/value
… and similarly for the other pins. Output confirmed with a LED and a voltmeter.